10.1 Introduction
10.2 Spontaneous Reaction and Equilibrium Condition
10.3 Change in G(ξ) with the Extent of Reaction
10.3.1 General Expression
for a
Mixture of Reacting Ideal Gases
10.3.2 Schematic Representation
10.4 Affinity10.3.2 Schematic Representation
10.5 Law of Mass Action for a Mixture of Gases
10.5.1 General Case
10.5.2 Other Forms of the Law of Mass Action
10.6 Chemical Equilibrium in the Presence of Pure Condensed Phases10.5.2 Other Forms of the Law of Mass Action
10.6.1 Chemical Potential
of a
Pure Condensed Phase. Activity
10.6.2 Law of Mass Action for Heterogeneous Systems
10.7 Independent Reactions10.6.2 Law of Mass Action for Heterogeneous Systems
10.7.1 General Remarks
10.7.2 Number and Nature of Independent Reactions
10.7.3 Verifying the Independence of Reactions
10.7.4 Consequences on Equilibrium and the Law of Mass Action
10.8 Phase Rule for Systems with Chemical Reactions10.7.2 Number and Nature of Independent Reactions
10.7.3 Verifying the Independence of Reactions
10.7.4 Consequences on Equilibrium and the Law of Mass Action
10.8.1 Demonstration
10.8.2 Examples of the Use of the Phase Rule
10.9 Effect of Temperature on the Equilibrium Constant10.8.2 Examples of the Use of the Phase Rule
10.10 Displacement Laws of Equilibria
10.10.1 Effect of
Temperature
10.10.2 Effect of Pressure
10.10.3 Effect of Volume
10.10.4 Effect of the Addition of an Inert Gas
10.10.5 Effect of an Excess in One of the Reacting Species at Constant Pressure
10.11 Reduction of Iron Oxides10.10.2 Effect of Pressure
10.10.3 Effect of Volume
10.10.4 Effect of the Addition of an Inert Gas
10.10.5 Effect of an Excess in One of the Reacting Species at Constant Pressure
10.11.1 Introduction and
Method
10.11.2 Reduction by Carbon Monoxide
10.11.3 Reduction by Hydrogen
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10.11.3 Reduction by Hydrogen
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main pageModified January 10 2007