Chapter 12  Non Ideal Solutions
12.1  Introduction
12.2  Variables and Excess Variables of Mixing
12.3  Effect of Temperature and Pressure on the Activity Coefficient
12.4  Standard State – Convention I for the Activity Coefficient
12.5  Applications of the Gibbs–Duhem Equation
12.5.1  Relation between Activity Coefficients in Binary Systems
12.5.2  Equilibrium Shift.  Azeotropy
12.6  Isothermal Diagram
12.7  Isobaric Diagram
12.8  Standard State – Convention II for the Activity Coefficient
12.9  Liquid – Liquid Extraction
12.10  Other Composition Scales and Standard States
12.10.1  Molality
12.10.2  Concentration
12.11  Law of Mass Action for Liquid Phase Systems
12.12  Electrolytes
12.12.1  General Considerations
12.12.2  Chemical Potential of Ions in Solution
12.12.3  Dissociation Equilibrium
12.12.4  Hydrogen Ion Convention for Aqueous Solutions
12.12.5  Electrode Potential
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Modified January 10 2007