5.1 Introduction
5.2 Closed Systems
5.2.1 Constant Volume
Process
(Isochoric Process)
5.2.2 Constant Pressure Process (Isobaric Process)
5.3 Characteristic Variables. Fundamental Equations. Open
Systems5.2.2 Constant Pressure Process (Isobaric Process)
5.3.1 Generalities
5.3.2 Internal Energy
5.3.3 Enthalpy
5.3.4 Helmholtz Function (Helmholtz Energy, Free Energy)
5.3.5 Gibbs Function (Gibbs Energy, Free Enthalpy)
5.3.6 Chemical Potential. Summary
5.4 Maxwell’s Relations5.3.2 Internal Energy
5.3.3 Enthalpy
5.3.4 Helmholtz Function (Helmholtz Energy, Free Energy)
5.3.5 Gibbs Function (Gibbs Energy, Free Enthalpy)
5.3.6 Chemical Potential. Summary
5.5 Thermodynamic Equation of State
5.5.1 General Case
5.5.2 Equation of State for an Ideal Gas
5.6 Properties of Cp
and CV5.5.2 Equation of State for an Ideal Gas
5.6.1 Relation between Cp and CV
5.6.2 Variation of CV with Volume and of Cp with Pressure
5.7 Physical Meaning of the Auxiliary Functions5.6.2 Variation of CV with Volume and of Cp with Pressure
5.7.1 Helmholtz Function
(Free
Energy, Helmholtz Energy)
5.7.2 Gibbs Function (Gibbs Energy, Free Enthalpy)
5.7.3 Spontaneous Evolution of a System. Equilibrium Condition
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5.7.3 Spontaneous Evolution of a System. Equilibrium Condition
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the main pageModified January 10 2007