8.1 Introduction
8.2 Differential Expressions of State Functions
8.2.1 Fundamental Relations
8.2.2 Chemical Potentials at Equilibrium
8.2.3 General Expressions for Open Systems
8.3 Spontaneous Transfer of a Species from One Phase to Another8.2.2 Chemical Potentials at Equilibrium
8.2.3 General Expressions for Open Systems
8.4 The Phase Rule
8.5 Equilibrium of Two Phases of a Pure Substance
8.5.1 The Clapeyron Equation
8.5.2 Equilibrium between a Gaseous Phase and a Condensed Phase (Liquid or Solid) of a Pure Substance
8.5.3 Schematic Representation of some of the Thermodynamic Functions in the Vicinity of a Phase Change
8.5.4 Effect of an Inert Gas on the Vapor Pressure of a Pure Substance
8.5.5 Effect of Temperature on the Latent Heat of Phase Change and on the Equilibrium Pressure
8.6 Phase Diagram of a Pure Substance8.5.2 Equilibrium between a Gaseous Phase and a Condensed Phase (Liquid or Solid) of a Pure Substance
8.5.3 Schematic Representation of some of the Thermodynamic Functions in the Vicinity of a Phase Change
8.5.4 Effect of an Inert Gas on the Vapor Pressure of a Pure Substance
8.5.5 Effect of Temperature on the Latent Heat of Phase Change and on the Equilibrium Pressure
8.6.1 The Solid Exists in
only
One Crystalline Form
8.6.2 The Solid May Exist in Several Crystalline Forms
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the main pageModified January 10 2007