Chapter   10.    Chemical Equilibria
10.1    Change in G(ξ) with the Extent of Reaction
10.1.1    Expression for a Mixture of Reacting Ideal Gases
10.1.2    Schematic Representation
10.2    Spontaneous Reaction.  Equilibrium
10.2.1    Isothermal Isobaric System
10.2.2    Isothermal Isochoric System
10.2.3    Adiabatic Isobaric System
10.2.4    Adiabatic Isochoric System
10.3    Law of Mass Action for a Gas Mixture
10.3.1    Standard Equilibrium Constant
10.3.2    Other Forms of the Law of Mass Action
10.4    Chemical Equilibrium in the Presence of Pure Condensed Phases
10.4.1    Chemical Potential of a Pure Condensed Phase
10.4.2    Law of Mass Action for Heterogeneous Systems
10.5    Independent Reactions
10.5.1    General Remarks
10.5.2    Number and Nature of Independent Reactions
10.5.3    Equilibrium of Systems where Several Reactions can Take Place Simultaneously
10.5.4    Consequences on Equilibrium
10.6    Phase Rule for Systems with Chemical Reactions
10.7    Effect of Temperature on the Equilibrium Constant
10.8    Displacement Laws of Equilibria
10.8.1    Effect of Temperature
10.8.2    Effect of Pressure
10.8.3    Effect of Volume
10.8.4    Effect of the Addition of an Inert Gas
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Modified January 10 2007