Chapter12.    Non Ideal Solutions
12.1    Introduction
12.2    Variables and Excess Variables of Mixing
12.3    Effect of Pressure and Temperature on the Activity Coefficient
12.4    Standard State – Convention I for the Activity Coefficient
12.5    Liquid – Vapor Equilibrium
12.5.1    Isothermal Diagram
12.5.2    Isobaric Diagram
12.6    Standard State – Convention II for the Activity Coefficient
12.7    Liquid – Liquid Extraction
12.8    Other Composition Scales and Standard States
12.8.1    Molality
12.8.2    Concentration
12.9    Law of Mass Action for Liquid Phase Systems
12.10    Electrolytes
12.10.1    General Considerations
12.10.2    Chemical Potential of Ions in Solution
12.10.3    Dissociation Equilibrium
12.10.4    Hydrogen Ion Convention for Aqueous Solutions
12.10.5    Electrode Potential

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Modified January 7 2007