5.1 Introduction
5.2 Closed Systems
5.2.1 Constant
Volume Process (Isochoric Process)
5.2.2 Constant Pressure Process (Isobaric Process)
5.2.3 Monobaric Process
5.3 Characteristic Variables. Fundamental
Equations. Open Systems. Systems with Chemical Reactions5.2.2 Constant Pressure Process (Isobaric Process)
5.2.3 Monobaric Process
5.3.1
Generalities
5.3.2 Internal Energy
5.3.3 Enthalpy
5.3.4 Helmholtz Energy (Helmholtz Function, Free Energy)
5.3.5 Gibbs Energy (Gibbs Function, Free Enthalpy)
5.3.6 Chemical Potential. Summary
5.4 Maxwell’s Relations5.3.2 Internal Energy
5.3.3 Enthalpy
5.3.4 Helmholtz Energy (Helmholtz Function, Free Energy)
5.3.5 Gibbs Energy (Gibbs Function, Free Enthalpy)
5.3.6 Chemical Potential. Summary
5.5 Thermodynamic Equation of State
5.5.1 General
Case
5.5.2 Equation of State for an Ideal Gas
5.6 Properties of Cp
and CV5.5.2 Equation of State for an Ideal Gas
5.6.1 Relation
between Cp and CV
5.6.2 Variation of CV with Volume and of Cp with Pressure
5.7 Physical Meaning of the Auxiliary Functions5.6.2 Variation of CV with Volume and of Cp with Pressure
5.7.1 Helmholtz
Energy (Helmholtz Function, Free Energy)
5.7.2 Differential Form
5.7.3 Gibbs Energy (Gibbs Function, Free Enthalpy)
5.7.4 Differential Form
5.7.5 Spontaneous Evolution and Equilibrium Condition
5.7.2 Differential Form
5.7.3 Gibbs Energy (Gibbs Function, Free Enthalpy)
5.7.4 Differential Form
5.7.5 Spontaneous Evolution and Equilibrium Condition
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main pageModified January 10 2007